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Particles and atomic structure

All matter is made of moving particles. Heating gives them more energy: solids melt, liquids boil. Diffusion and Brownian motion are evidence that particles move.

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The kinetic particle theory

All matter is made of moving particles. Heating gives them more energy: solids melt, liquids boil. Diffusion and Brownian motion are evidence that particles move.

The atom

  • Proton: +1, mass 1, in the nucleus.
  • Neutron: 0, mass 1, in the nucleus.
  • Electron: −1, mass 1/1840, in shells around the nucleus.

Proton (atomic) number Z = number of protons. Nucleon (mass) number A = protons + neutrons.

Isotopes

Atoms of the same element with the same number of protons but different numbers of neutrons, e.g. ³⁵Cl and ³⁷Cl. They have the same chemical properties.

Relative atomic mass is the average mass of an element's isotopes compared with 1/12 of a carbon-12 atom.

Worked example: Chlorine is 75% ³⁵Cl and 25% ³⁷Cl. Find its relative atomic mass.

Ar = (75 × 35 + 25 × 37) ÷ 100 = (2625 + 925) ÷ 100 = 35.5

Electron configuration

Shells hold 2, 8, 8 electrons (first 20 elements). Potassium (Z = 19) is 2,8,8,1. The outer electrons decide chemical properties.

Exam tip: For an ion, adjust the electrons: Na⁺ has 10 electrons (2,8), Cl⁻ has 18 (2,8,8).

Check yourself

  1. How many neutrons are in ²⁷Al (Z = 13)?
  2. Write the electron configuration of calcium (Z = 20).
  3. Define isotopes.
Show answers
  1. 27 − 13 = 14
  2. 2,8,8,2
  3. Atoms of the same element with the same number of protons but different numbers of neutrons.
Next topicChemical bonding and structure

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