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States of matter and experimental techniques

Kinetic particle theory: arrangement, motion and energy of particles in solids, liquids and gases; changes of state (melting, boiling, evaporation, condensation, freezing, sublimation); diffusion – lighter gas molecules diffuse faster.

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States of matter

Kinetic particle theory: arrangement, motion and energy of particles in solids, liquids and gases; changes of state (melting, boiling, evaporation, condensation, freezing, sublimation); diffusion – lighter gas molecules diffuse faster.

Measurement

Apparatus for time, temperature, mass and volume (burettes, pipettes, measuring cylinders, gas syringes).

Purity

Pure substances have sharp melting and boiling points; impurities lower the melting point and raise the boiling point.

Separation techniques

Filtration, crystallisation, simple distillation, fractional distillation (crude oil, liquid air), and paper chromatography.

  • Rf value = distance moved by substance ÷ distance moved by solvent front.

Worked example: A spot moves 3.6 cm while the solvent moves 9.0 cm. Find the Rf value.

Rf = 3.6 ÷ 9.0 = 0.40

  • Locating agents reveal colourless spots (e.g. ninhydrin for amino acids).
Exam tip: Choose the separation method by the property that differs: solubility, boiling point or how far a substance travels in chromatography.

Check yourself

  1. How does an impurity affect the melting point of a substance?
  2. Which technique separates ethanol from water?
  3. Why does ammonia diffuse faster than hydrogen chloride?
Show answers
  1. It lowers it and makes it melt over a range.
  2. Fractional distillation.
  3. Ammonia molecules have a lower relative molecular mass, so they move faster.
Next topicAtoms, elements, compounds and bonding

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