Topic 3 of 8 · Form 3
Stoichiometry and the mole concept
Balanced equations with state symbols; ionic equations (e.g. Ag⁺(aq) + Cl⁻(aq) → AgCl(s)).
Notes for this topic 1 file, in order
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Formulae and equations
Balanced equations with state symbols; ionic equations (e.g. Ag⁺(aq) + Cl⁻(aq) → AgCl(s)).
The mole
n = m/Mᵣ; gas volume = n × 24 dm³ at r.t.p.; concentration c = n/V (mol/dm³) or g/dm³.
Worked example: What mass of calcium oxide is produced by heating 50 g of calcium carbonate? (Ca = 40, C = 12, O = 16)
CaCO₃ → CaO + CO₂; n(CaCO₃) = 50 ÷ 100 = 0.50 mol → n(CaO) = 0.50 mol → mass = 0.50 × 56 = 28 g
Empirical and molecular formulae; percentage composition
Titration calculations
Worked example: 20.0 cm³ of 0.100 mol/dm³ HCl neutralises 25.0 cm³ of NaOH. Find the NaOH concentration.
n(HCl) = 0.00200 mol = n(NaOH) → c = 0.00200 ÷ 0.0250 = 0.0800 mol/dm³
Yield and purity
Percentage yield = actual ÷ theoretical × 100; percentage purity = mass of pure substance ÷ mass of sample × 100.
Limiting reactants
Identify which reactant runs out first using mole ratios.
Check yourself
- Find the number of moles in 4.4 g of CO₂.
- What volume does 0.25 mol of gas occupy at r.t.p.?
- Find the percentage by mass of nitrogen in NH₄NO₃ (N = 14, H = 1, O = 16).
Show answers
- 0.10 mol
- 6.0 dm³
- 28 ÷ 80 × 100 = 35%
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